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For starting an interactive Mathematica session on the login node, you first need to load the Mathematica module. Afterwards you can start the application with the command math

[leonhard@euler04 ~]$ module load mathematica/10.2.0
[leonhard@euler04 ~]$ math
Mathematica 10.2.0 for Linux x86 (64-bit)
Copyright 1988-2015 Wolfram Research, Inc.

In[1]:= N[E,100]                                                                                                              

Out[1]= 2.718281828459045235360287471352662497757247093699959574966967627724076630353547594571382178525166427

Please only do small tests in interactive sessions. Larger computations must be submitted as a batch job.